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Showing posts with label GENERAL ORGANIC CHEMISTRY. Show all posts
Showing posts with label GENERAL ORGANIC CHEMISTRY. Show all posts
Monday, October 21, 2024

The remarkable basicity of guanidine

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The remarkable basicity of guanidine is attributed to the fact that the positive charge on the guanidinium ion is delocalized equally over t...
Tuesday, August 20, 2024

Basic strength order of (1). aniline 2). 2,6-dimethyl-aniline (3). 1,1-dimethyl aniline (4). 2,6,1,1-dimethyl aniline are?

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Sunday, August 18, 2024

Ortho effect (SIP) in ortho Substituted aniline:

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Ortho effect in case of ortho substituted aniline is also known as steric Inhibition of protanation (SIP). In ortho substituted ...

Ortho Effect: SIR effect: SIP effect:

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The presence of a substituent at Ortho-position of aromatic acid increases the acidic character by steric inhibition of resonance(SIR). This...
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