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Showing posts with label
COORDINATION COMPOUNDS:
.
Show all posts
Showing posts with label
COORDINATION COMPOUNDS:
.
Show all posts
Friday, December 20, 2024
Turnbull Blue: Charge transfer from metal to metal: Colour due CTS :
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Ferrous (Fe^+2) salt reacts with potassium ferricyanide to form a blue precipitate which is called Turnbull's blue. The reaction is as...
Prussian Blue: Charge transfer from metal to metal: Colour due CTS :
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Prussian blue is formed when ferric(Fe^3) salt reacts with ferrocyanide. Here we see both oxidation states of iron but only +2 oxidation s...
Tuesday, December 10, 2024
Splitting of d-Orbital in squar planar complexes.
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As the lobes of d x^ 2 − y^ 2 point towards the ligands , this orbital has highest energy . The lobes of d x y orbital lie between the l...
What is synergic bonding , Bonding in metal Carbonyl , Bond order of M-C and C-O in synergic Bond
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(1) Stretching frequency of CO is inversely proportional to negative oxidation state of central metal atom (2) Extent of back bondi...
Sunday, December 8, 2024
What is Hybrization and magnatic behaviour of [NiF6]-2 complex ?
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[NiF6]-2 : This is the exceptional case: Here F^-1 work as strong field ligand due to presence of high charge hence Zeff is also high in t...
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