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Showing posts with label STRUCTURE OF ATOM:. Show all posts
Showing posts with label STRUCTURE OF ATOM:. Show all posts

Thursday, June 18, 2020

If H+ (ion) is accelerated to a final velocity of 6.62×10+6 meter per second and error in velocity is 1% then find uncertainty in position is?


What is the relation between Total energy (TE), Kinetic energy (KE) and Potential energy (PE) of Bohr's orbits?

Relation between Total energy (TE), Kinetic energy (KE) and Potential energy (PE):


Important conclusions:
(1) The minus sign for the energy of an electron in an orbit represents attraction between the +vely charged nucleus and negatively charged electron.
(2) Energy of an electron at infinite distance from the nucleus is zero.
(3) As an electron approaches the nucleus, the electrical attraction increases, energy of electron decreases and it becomes negative.
(4) Energy of an electron increases as the value of ‘n’increases i.e.
(5) Value of ‘n’ remaining unchanged, the amount of energy associated with an electron remains unaltered.
(6) Energy of electron in firstsecondthird and fourthorbit are –13.6, –3.4, –1.5, and –0.85 eV/atomrespectively.
(7) Although the energy of electron increases with increase in the value of ‘n’ (orbit), yet the difference of energy between successive orbits decreases. Thus E2 – E1 > E3 – E2 > E4 – E3 > E5 – E4 >, etc…

How to calculate energy of Bohr's orbits in term of Rydberg's constant

Energy in term of Rydberg’s Constant:

Which of the Hydrogen spectrum series found in visible range of spectrum?

Balmer series of Hydrogen spectrum found in visible range of spectrum while lymen series found in UV range of spectrum and remain series of spectrum found in Infra red of spectrum..
More over only first four line of Balmer series found in visible range and others line of Balmer series Lines  also found infrared part of spectrum.

Friday, June 21, 2019

ENERGY IN BOHR'S ORBITS:


­­Total energy of (E) of an electron revolving in nth orbit is equal to sum of kinetic energy and Potential energy.
We know the electron revolve around nucleus due balancing of two forces columbic and centrifugal forces

This is the famous Bohr’s equation applicable to Hydrogen like atoms or ions as He+1, Li+2 , Be+3 
etc.
The factor (4 pi epsilon zero) is known as permittivity factor and its numerical value is 1.11268*10-10C2N-1M-2  ( In CGS Unit K= 1)
Pi= 22/7= 3.424, me=9.109 *10-31 kg, e = 1.602 *10-10 C and h= 6.626*10-34 j-s
Calculation of En in SI Unit:
Bohr’s energy in electron volt:
We know that, 1eV = 1.602 *10-19 J hence
Energy in term of Rydberg’s Constant:

Relation between Total energy (TE), Kinetic energy (KE) and Potential energy (PE):


Important conclusions:
(1) The minus sign for the energy of an electron in an orbit represents attraction between the +vely charged nucleus and negatively charged electron.
(2) Energy of an electron at infinite distance from the nucleus is zero.
(3) As an electron approaches the nucleus, the electrical attraction increases, energy of electron decreases and it becomes negative.
(4) Energy of an electron increases as the value of ‘n’ increases i.e.
(5) Value of ‘n’ remaining unchanged, the amount of energy associated with an electron remains unaltered.
(6) Energy of electron in first, second, third and fourth orbit are –13.6, –3.4, –1.5, and –0.85 eV/atom respectively.
(7) Although the energy of electron increases with increase in the value of ‘n’ (orbit), yet the difference of energy between successive orbits decreases. Thus E2 – E1 > E3 – E2 > E4 – E3 > E5 – E4 >, etc….

Wednesday, February 20, 2019

HEISENBERG'S UNCERTAINTY PRINCIPLE:

"It is not possible to determine simultaneously the exact position and exact moment of a particle as small as an electron"
ILLUSTRATIVE EXAMPLE (1): If error in position of an electron is 0.33 pm, what will be the error in its velocity? (1 pm=10-12

ILLUSTRATIVE EXAMPLE (2): If H+ (ion) is accelerated to a final velocity of 6.62×10+6 meter per second and error in velocity is 1% then find uncertainty in position is?
ILLUSTRATIVE EXAMPLE (3): Radius of nucleus is the order of 10-13 cm (10-15 m) and thus on the basis of Heisenberg's uncertainty principle .show that electron cannot exist within the atomic nucleus?
SOLUTION:
ILLUSTRATIVE EXAMPLE (4): If uncertainty in position and momentum of electron  are equal then prove that uncertainty in velocity  is ...
SOLUTION:
ILLUSTRATIVE EXAMPLE (5):If uncertainty in momentum of an electron are three times of uncertainty in position then uncertainty in velocity of electron would be  
SOLUTION:
ILLUSTRATIVE EXAMPLE (6): What is the uncertainty of Photon in position of  wave length 500 A .If wave length is known to an accuracy of 1pm. 
SOLUTION:
ILLUSTRATIVE EXAMPLE (7): An electron is accelerated by (V) volt and following graph is obtained calculate the (V) voltage?
SOLUTION:
ILLUSTRATIVE EXAMPLE (8): A electron having velocity 2×10+6 m/s has uncertainty in kinetic energy is 6.62/π×10-34 j, than calculate the uncertainty in position of electron in Anstrom .
SOLUTION:
ILLUSTRATIVE EXAMPLE (9): Two particles A and B are in motion .if the wave length associated with particle A is 5×10-8 m. Calculate the wave length associated with particle B if momentum is Half of A?
SOLUTION:
ILLUSTRATIVE EXAMPLE (10): If uncertainty in position of an moving electron is equal to its de Broglie wave length, then its velocity will be completely uncertain. Explain?
SOLUTION:
ILLUSTRATIVE EXAMPLE (11): If the de Broglie wave length of a particle of mass (m) is 100 times of its Velocity. Then its value in term of its mass (m) and plank constant (h) is?