SOLUTION: Sulphide ion (S2-) is less basic than oxide ion (O2-) due to its larger size. the oxide ion has a higher charge density than the sulphide ion hence the small H+ more attracted toward smaller ion (O2-) .
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Monday, January 11, 2021
Which is more basic oxide ion (O-2 ) or hydroxide ion( OH- ) and why ?
SOLUTION: The basic strength of base primarily depends on the ability of a species to attract H+, which is also depends upon electrostatic interactions. The smaller and more highly charged a negative species is, the stronger the attraction for the small, positive H+ ion. For example, O2- has a higher negative charge than OH-, and as a result it is a stronger base. One does not normally expect reactions that take place in aqueous solutions to produce oxides as a result of the basicity of O2-. Ionic oxides normally react with water to produce hydroxides:
CaO + H2O → Ca(OH)2
Topic:
ACIDS AND BASES,
INORGANIC MECHANISM:
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