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Monday, April 20, 2020
The ammonia prepared by treating ammonium sulphate with calcium hydroxide is completely used by NiCl2.6H2O to form a stable coordination compound. Assume that both the reactions are 100% complete. If 1584 g of ammonium sulphate and 952g of NiCl2.6H2O are used in the preparation, the combined weight (in grams) of gypsum and the nickel-ammonia coordination compound thus produced is___. (Atomic weights in g mol–1: H = 1, N = 14, O = 16, S = 32, Cl = 35.5, Ca = 40, Ni = 59) (JEE-ADVANCED 2018 PAPER-2)
Galena (an ore) is partially oxidized by passing air through it at high temperature. After some time, the passage of air is stopped, but the heating is continued in a closed furnance such that the contents undergo self-reduction. The weight (in kg) of Pb produced per kg of O2 consumed is______ . (Atomic weights in g mol–1 : O = 16, S = 32, Pb = 207). (JEE-Advanced 2018 Paper-2)
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