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Tuesday, December 10, 2024
What is synergic bonding , Bonding in metal Carbonyl , Bond order of M-C and C-O in synergic Bond
(1) Stretching frequency of CO is inversely proportional to negative oxidation state of central metal atom
(2) Extent of back bonding or back acceptance is directly proportional to negative oxidation state of central metal atom.
(3) M-C bond order is directly proportional to negative oxidation state of central metal atom
(4) C-O bond order is inversely proportional to negative oxidation state of central metal atom.
(5) d C-O bond length is directly proportional to negative oxidation state of central metal atom.
(6) Bond energy of C-O bond is inversely proportional to negative oxidation state of central metal atom
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COORDINATION COMPOUNDS:
What is the heating effect on the nitrates of the alkali metals like Li, Na, K, Cs and Rb etc.
Nitrates are prepared by the action of nitric acid on a metal or its oxide, hydroxide or carbonate. All nitrates are soluble in water. On heating, the nitrates of the alkali metals yield only oxygen and the nitrite (Except Lithium).
Most of the nitrate salts of other metals on heating decompose to produce metal oxide ,nitrogen dioxide (NO2) and oxygen gas. (Except M= Na, K, Rb, Cs but lithium(Li) do as above)
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Heating effects on salts:
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