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Tuesday, December 10, 2024

Splitting of d-Orbital in squar planar complexes.

As the lobes of dx^2y^2 point towards the ligands , this orbital has highest energy . The lobes of dxy orbital lie between the ligands but are coplanar with them orbital is next highest energy . The lobes of dz^2 orbital point out of the plane of the complex but the belt around the centre of the orbital (which contain 1/3 of the electron density ) lies in the plane. Therefore dz^2 orbital is the next highest in energy. The lobes of dzx and dzy orbitals point out of the plane of the complex . Hence , they are least affected by the electrostatic field of the ligands. They are degenerate and lowest in energy .

What is synergic bonding , Bonding in metal Carbonyl , Bond order of M-C and C-O in synergic Bond


(1) Stretching frequency of CO is inversely proportional to negative oxidation state of central metal atom

(2) Extent of back bonding or back acceptance is directly proportional to negative oxidation state of central metal atom.

(3) M-C bond order is directly proportional to negative oxidation state of central metal atom

(4) C-O bond order is inversely proportional to negative oxidation state of central metal atom.

(5) d C-O bond length is directly proportional to negative oxidation state of central metal atom.

(6) Bond energy of C-O bond is inversely proportional to negative oxidation state of central metal atom 





What is the heating effect on the nitrates of the alkali metals like Li, Na, K, Cs and Rb etc.

Nitrates are prepared by the action of nitric acid on a metal or its oxide, hydroxide or carbonate. All nitrates are soluble in water. On heating, the nitrates of the alkali metals yield only oxygen and the nitrite (Except Lithium).

Most of the nitrate salts of other metals on heating decompose to produce metal oxide ,nitrogen dioxide (NO2) and oxygen gas. (Except M= Na, K, Rb, Cs but lithium(Li) do as above)