This reaction is not preferred when base sensitive groups like halogens or bulky groups are present.
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Thursday, July 3, 2025
Clemmensen reduction: reduction of an aldehyde or a ketones with zinc amalagam and concentrate Hydrochloric (HCl) acid.
Note; Clemmensen reduction not suitable for those compound having acid sensitive groups ( basic in nature) such as Alcohol, amines, alkenes, ester, cyclic ketal, nitro etc.
Topic:
CORBONYL COMPOUNDS,
Name reactions
Sunday, June 29, 2025
In The Cannizzaro, The intermediate That will be The best hydride donor is:
Ans (3) Dioxide anion is a better hydride doner, and presene of -OCH3, group further increases the electron density.
Note: Dioxide anion form in cannnizzaro reaction when concentration of Base taken high and the reaction becomes 4rth order reaction.
Topic:
Cannizzaro reactions,
Name reactions
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