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Thursday, September 24, 2020

A gas occupied a volume of 250 ml at 700 mm Hg pressure and 25°C. What additional pressure is required to reduce the gas volume to its 4/5th value at the same temperature


A sample of a given mass of a gas at a constant temperature occupies 95cm3 under a pressure of 9.962 × 104N/m2 .At the same temperature, it volume at a pressure of 10.13 × 104 N/m2 is :


Calculate the mass of mercuryin a uniform column, 760 mm high and 1.00 cm2 in cross-sectional area. Is there any change in (a) mass and (b) pressure of column of same height but with 2.00 cm2 cross sectional area is taken ? (density of Hg = 13.6 g/cm3 )


What is Vander waals equation of state of a real gas ?

Vander Waals Equation of State for a Real Gas: The equation of state generated by Vander
Waals in 1873 reproduces the observed behaviour with moderate accuracy. For n moles of gas,
the Vander Waals equation is


1 mole of CCl4 vapours at 77oC occupies a volume of 35.0 L. If vander waal’s constants are a = 20.39 L 2 atm mol–2 and b = 0.1383 L mol–1, calculate compressibility factor Z under (a) low pressure region. (b) high pressure region.