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Wednesday, December 30, 2020

What is Hypervalent species or compounds?

The compounds or ions which doesn't follow octet rule inspire of that contains more than eight electrons and also stable called Hypervalent species.

For examples XeFe2(10e), XeFe4(12e), SF4(10e), SFe6(12e), IFe7(14e), I2Cl6(10e), TeF5(12e) etc

Hypervalent species may act as Lewis acid but not always.


Tuesday, December 29, 2020

Cage like Structure

P4, P4O4, P4O10, P4S3, P4S10, N4(CH2)6

Structure of P4O6 and P4O10

Normal Oxides:

The Oxides in which oxidation state of central atom is found to be one of the it's common oxidation state. The are also called acid anhydrides because on dissolving them  into water oxygen acid is formed in which oxidation state of central atom is found to be same as present in Oxide.

Examples:  B2O3, CO2, N2O3, N2O5, SO2, SO3, Cl2O7, XeO3, XeO4 etc.


Peroxides

The oxides in which  calculated oxidation state of central atom is more than maximum oxidation state of central atom due to the presence of peroxide linkage.

For examples, H2O2, Na2O2, BaO2, PbO2, CrO5 etc.

Suboxides:

The oxides contains more oxygen atoms as compare to central atoms and according to valency requirements of central atoms number of oxygen atoms are not sufficient.

For examples B2O3, C3O2, C12O9, Pb3O, Rb9O2, Cs11O3 etc.