In case of [Ni(CN)4]-2 Ni is in +2 and
3d8 configuration but presence
of strong ligand (CN) , the two unpaired electron in the 3d orbital pair up
thus there is no unpaired electrons present hence it is colourless.
In case of [Ni(H2O)4]+2 Ni is in +2 and
3d8 configuration and two
unpaired electrons which I do not pair up in the presence of weak ligand
(H2O) , hence it is colour due to d-d transition , red colour light is absorbed and give it
complementary colour green.
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