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Friday, May 7, 2021

Two weak acid solution HA1 and HA2 each with same concentration and having Pka values 3 and 5 are placed in contact with hydrogen electrode ( 1 atm at 25 degree) and are interconnected through a salt bridge find the emf.

Consider the cell:

                        Pt H2(1atm)IHA2(1M) II HA1(1M)IH2(1 atm)Pt

               Given that    PKa1 of HA1 is = 3 (at Cathode)

                                      Pka2 for HA2 is = 5 (at anode)


Related Questions:

(1) The conductivity of 0.0011028 mol per liter acetic acid is 4.95 × 10–5 S per cm. Calculate its dissociation constant if ^°m for acetic acid is 390.5 S cm2 per mol–1 .


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