Illustrative solution:
Applying
POAC on (P) atoms:
P à H3PO4
Numbers of
moles of (P) atoms in P4 = Numbers of moles of (P) atoms in H3PO4
4x
nP4= 1x nH3PO4
Applying
POAC on (H) atoms:
1x nHNO3
= 3 x nH3PO4 + 2 x nH2O
Applying
POAC on (N) atoms:
1 x nHNO3
= 1 x nNO2
Applying
POAC on (O) atoms:
3 x nHNO3
= 4 x nH3PO4 +2 x nNO2 + 1nH2O
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