Tropylium is
highly stable due to conjugated system, that being resonance stabilized
and the number of canonical forms of tropylium is more. But it is less stable
than tricyclopropylmethyl carbocation because tricyclopropylmethyl carbocation
undergoes a strong stability mechanism
factor that is sigma resonance or dancing resonance (sigma-tropic rearrangement ).
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Monday, December 23, 2019
Sunday, December 22, 2019
What is Bredt's rule ?
According to
Bredt’s rule a bridgehead carbon atom of bicyclo compound cannot be sp2
hybridised or in other word a bridgehead carbon atom cannot be form double bond.
unless the ring that contains at least eight atoms
In Other word Bredt's rule state that planarity is not possible at bridge head carbon of bicyclo compound till one of the ring size is (8) eight member or more.
ILLUSTRATIVE EXAMPLE: Bredt's use for the predicting major and minor product of elimination reactions.
Topic:
GENERAL ORGANIC CHEMISTRY
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