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Sunday, January 26, 2020

Give the products formed on heating of 1,1,2-cyclohexane tricarboxylic acid.

First Geminal acid on heating undergo decarboxylation to formed 1,2-Cyclohexane Dicarboxylic acid, which is on further heating gives corresponding anhydride.

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How can explain that Chloral hydrate is stable Compound although it has two -OH groups attached to same carbon?

Chloral hydrate (CH3-CHO.2H2O) has unusual stability due to -I effect of three Chlorine atoms, which leads to the formation of two Hydrogen bond. The energy released in the formation of three bonds provides extra stability.