We know that N is less electronegative than oxygen therefore. N can donate a pair of electrons more readily than
oxygen. Therefore, magnitude of positive charge on carbonyl carbon in benzamide is less than in methyl benzoate. Thus during
hydrolysis, attack of -OH- ion on carbonyl carbon in benzamide
is difficult than
in methyl benzoate. Thus benzamide is less easily hydrolysed than methyl
benzoate.
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