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Saturday, February 8, 2020

How to write the mechanism of ring expansion in organic chemistry?

  1. How to write dehydration and ring expansion mechanism of 1-(1-cyclopentyl) methanol?
  2. How to write dehydration and ring expansion mechanism of Tetrahydrofurfuryl alcohol?
  3. How to write dehydration and ring expansion mechanism of 2-cyclopentylethanol?
  4. Write the Dehydration and ring expansion mechanism of following alcohol:
  5. Write Dehydration and ring expansion mechanism of 1-cyclobutylethanol in the presence of con H2SO4.
  6. Explain the ring expansion mechanism of Bicyclic 1,2-Diols which undergoes pinacol pinacolone mechanism?
  7. Explain Dehydration and ring expansion mechanism of 1-(1-Methylcyclopentyl)ethan-ol?
  8. Write the major and minor product of hydration of 1 -Methylcyclopent-1-ene in acidic medium?
  9. Write the major and minor product of hydrohalogenation of 2-Methylbut-1-ene in acidic medium?
  10. To synthesize 2, 3-dimethylbut-1-ene in the better yield dehydrohalogenation of 2, 3-dimethyl-1-bromobutane is preferred over dehydration of 2, 3-dimethylhutan-1-ol. Why ?
  11. Why dehydration proceeds in acid but not in base?
  12. Why alcohols do not undergo base induced dehydration in the same way that alkyl halides are dehydrohalogenated ?
  13. How can write dehydration mechanism of 1,2,3-Trihydroxymethylcyclopropane into Benzene in acidic medium?

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