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Which will have very fast tendency to dimerized ClO2 or NO and why?

In case of ClO2 odd electron is delocalized over 3 atoms so extent of delocalization of odd electron is higher in comparison to NO. Hence tendency of demerisation of a NO is faster that of ClO2.

We know that tendency of demerisation of ClO2 is very poor rather negligible at normal condition as odd electron is delocalized over entire molecule however below -180 it has been found in dimeric form.

Related Questions:
Although electron affinity of chlorine is higher than fluorine, yet fluorine act as better oxidizing agent than chlorine? Explain.

Why chlorine trifluoride (ClF3) exists but fluorine trichloride (FCl3) does not?

Why Chlorine (Cl2) bleaches a substance permanently but sulphuredioxide (SO2) does it temporarily?

What is the correct order of electronegativity of Cl atoms in HClO, HClO2, HClO3 and HClO4 ?

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