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Saturday, June 6, 2020

What is the effect of temperature and pressure on crystal structure of Caesium Chloride?

Effect of temperature on crystal structure:
Increase of temperature decreases the coordination of number, e.g. upon heating to
760 K, the CsCl type crystal structure having coordination 8:8 changed to NaCl type crystal structures having coordination 6:6.
Effect of pressure on crystal structure:
Increase of pressure increases the Co – ordination number during crystallization e.g. by applying pressure, the NaCl type crystal structure having 6:6 coordination number changes to CsCl type crystal having coordination number 8:8
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