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Tuesday, February 2, 2021

What is structure of Al2Cl6 and also explain bridge bond in Al2Cl6?

AlCl3 dimmerised to Al2Cl6 by 3C-4e bond bridge bond and Al2Cl6 is neither hypovalent nor hypovalent rather its octet is complete. Al2Cl6 contains six bond having two bridge bond(3c-4e) and four bond is (2C-2e).

We will used  MOT here  it cannot act as Lewis acid  due to crowding in spite having vacant d orbital’s however AlCl3 act as Lewis acid.

Related Questions:

What is the difference between the structure of AlCl3 and diborane?

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