What is structure of Al2Cl6 and also explain bridge bond in Al2Cl6?

AlCl₃ dimmerised to Al₂Cl₆ by 3C-4e bond bridge bond and Al₂Cl₆ is neither hypovalent nor hypovalent rather its octet is complete. Al₂Cl₆ contains six bond having two bridge bond(3c-4e) and four bond is (2C-2e).

We will used  MOT here  it cannot act as Lewis acid  due to crowding in spite having vacant d orbital’s however AlCl₃ act as Lewis acid.

Related Questions:

(1) What is the difference between the structure of AlCl3 and diborane?

(2) What is structural feature of monomeric and polymeric Beryllium halides ?

(3) What is bridge bond ? explaine 3C-4e bridge bond with suitable examples .

(4) What is structure of Beryllium chloride ?

(5) What is the structure of Aluminium tetrahydridoborate (Al(BH4)3) ?

(6) What is structure of Al(CH3)3 and also explain the bridge bonding in Al(CH3)3?

(7) The type of overlap in the bridge bond exist in Al2(CH3)6 is

(8) What is structure of diborane?

(9) What is structure of BeH2 in solid state ?

(10) Consider the structure of Al(CH3)3 given below and select the correct option?

(11) Consider Al2(OH)6 compound and calculate the value of (X+Y)/Z Where X= total number of two centre-two electrons (2C-2e) bond, Y= total number of three centre-two electron(3C-2e)bonds, and Z=total number of three centre-four electron (3C-4e) bond;