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Friday, May 14, 2021

How many gram Cu will deposited by passing 2 Amp for 30 minutes in aq solution of CuSO4. What will be weight of O2 produced at anode?


Related Questions:

(1) A current of 2.68 ampere is passed for one hour through an aqueous solution of copper sulphate using copper electrodes. Calculate the change in the mass cathode and that of anode. ( atomic mass of copper is 63.5 u).

(3) On passing 3 faradays of electricity through three electrolytic cells connect in series containing Ag+ , Ca+2 and Al+3 ions respectively , the molar ratio in which three metals ions are liberated at the electrode is





Tuesday, May 11, 2021

Find the Volume of gas evolved by passing 0.965 Amp current for 1 hour through an aqueous solution CH3COONa at 250c and 1 atm?


Related Questions:

(1) A current of 2.68 ampere is passed for one hour through an aqueous solution of copper sulphate using copper electrodes. Calculate the change in the mass cathode and that of anode. ( atomic mass of copper is 63.5 u).

(3) On passing 3 faradays of electricity through three electrolytic cells connect in series containing Ag+ , Ca+2 and Al+3 ions respectively , the molar ratio in which three metals ions are liberated at the electrode is

During electro refining of Cu how much time is needed to produce 250g Cu on the cathode if the current is kept at 11 A?

Given that current (i) = 11 A = 11 cycle/second

Number of moles of copper deposited on cathode is 


Related Questions:

(1) A current of 2.68 ampere is passed for one hour through an aqueous solution of copper sulphate using copper electrodes. Calculate the change in the mass cathode and that of anode. ( atomic mass of copper is 63.5 u).

(3) On passing 3 faradays of electricity through three electrolytic cells connect in series containing Ag+ , Ca+2 and Al+3 ions respectively , the molar ratio in which three metals ions are liberated at the electrode is

Zn amalgam is prepared by electrolysis of aqueous ZnCl2 using 9 gram Hg cathode. How much current is to be passed through ZnCl2 solution for 1000 seconds to prepare of Zn amalgam with 20% weight? (Atomic wt, Zn = 65.4 g)

 Let “x “gram of Zn deposited on 9 gm of Hg:


Related Questions:

(1) A current of 2.68 ampere is passed for one hour through an aqueous solution of copper sulphate using copper electrodes. Calculate the change in the mass cathode and that of anode. ( atomic mass of copper is 63.5 u).

(3) On passing 3 faradays of electricity through three electrolytic cells connect in series containing Ag+ , Ca+2 and Al+3 ions respectively , the molar ratio in which three metals ions are liberated at the electrode is



Monday, May 10, 2021

1 M aqueous solution of NaCl undergo electrolysis if 50 mA current is passed for 12 hours assume current efficiency is 25%. The total volume of gas produced at standard state is. NaCl (aq) solution undergoes electrolysis as:

NaCl(aq) àNa+ + Cl-

        H2O à H+ + HO-

Reactions:

At cathode: 2H+ + 2e-à H2(g)

At anode:   2Cl-à Cl2(g) + 2e-


Related Questions:

(1) A current of 2.68 ampere is passed for one hour through an aqueous solution of copper sulphate using copper electrodes. Calculate the change in the mass cathode and that of anode. ( atomic mass of copper is 63.5 u).


How long has a current of 3 ampere to be applied through a solution of silver nitrate to coat a metal surface of 80 cm2 with 0.005 cm thick layer density of silver is 10.5g/cm3.

Given Area = 80 cm3

   Thickness = 0.0005 cm

        Density= 10.5 gl cm3

Thus Mass of silver deposited on cathode is = 80 cm3 x 0.0005 cm x10.5 gm/cm3= 0.42 gm

Related Questions:


0.5 faraday of electricity was passed to deposit all the copper present in 500 ml of CuSO4 solution. What was the Molarity of this solution?

 

Related Questions:

(1) A current of 2.68 ampere is passed for one hour through an aqueous solution of copper sulphate using copper electrodes. Calculate the change in the mass cathode and that of anode. ( atomic mass of copper is 63.5 u).

Ag is electrodeposited on a vessel of total surface area 800 cm2 by passing current of 0.2 A for 3 hrs. Calculate thickness of Ag deposited. (Density Ag = 9.67 g/ml).

 


(1) A current of 2.68 ampere is passed for one hour through an aqueous solution of copper sulphate using copper electrodes. Calculate the change in the mass cathode and that of anode. ( atomic mass of copper is 63.5 u).

In Arrhenius equation for a certain reaction, the value of A and Ea (activation energy) are 4x 10^13 sec^-1 and 98.6 kJ mole^-1 respectively. At what temperature, the reaction will have specific rate constant 1.1x 10^-3 sec^-1.

 Arrhenius equation:

The temperature dependence of rate of a chemical reaction can be accurately explained by Arrhenius equation. It was first proposed by Dutch chemist   J.H. Vant’s Hoff but Swedish chemist Arrhenius provides its physical justification and interpretation.

                            

Where  

 K= Rate constant

 A= Arrhenius constant or frequency factor or pre exponential factor

 R= Universal gas constant =25/3 joule per mole per second

Ea= Activation Energy

 T= temperature

-Ea/RT= Boltzmann factor or fraction of molecule having equal or greater than Activation energy or fraction of molecule that have kinetic energy greater than activation energy.


Related Questions:

(1) What is Arrhenius equation ?

(2) what happen when activation energy of a chemical reaction becomes equal to RT?

(3) What is the activation energy and how to different from threshold energy ?

(4) In Arrhenius equation for a certain reaction, the value of A and Ea (activation energy) are 4 × 10^13 sec–1 and 98.6 kJ mol–1 respectively. At what temperature, the reaction will have specific rate constant 1.1 × 10^–3 sec–1?

(5) The energy of activation for a reaction is 100 kJ mol–1. Presence of a catalyst lowers the energy of activation by 75%.What will be effect on rate of reaction at 20ºC, other things being equal?

(6) A drug becomes ineffective after 30 % decomposition. The original concentration of a sample was 5mg/mL which becomes 4.2 mg/mL during 20 months. Assuming the decomposition of first order , calculate the expiry time of the drug in months. What is the half life of the product?

(7) A first order reaction is 20 % completed in 10 minutes. Calculate the time taken for the reaction to go to 80 % completion. 

(8) The rate of a reaction triple when temperature changes from 20”C to 50”C. Calculate energy of activation for the reaction (R = 8.314 JK^1 mol^1).

 

Sunday, May 9, 2021

A current of 2.68 ampere is passed for one hour through an aqueous solution of copper sulphate using copper electrodes. Calculate the change in the mass cathode and that of anode. ( atomic mass of copper is 63.5 u).


Related Questions:

(1) The conductivity of 0.0011028 mol per liter acetic acid is 4.95 × 10–5 S per cm. Calculate its dissociation constant if ^°m for acetic acid is 390.5 S cm2 per mol–1 .


What current strength ampere will be require to liberate 10 gm chlorine from sodium chloride solution in one hour?

 

Related Questions:

(1) The conductivity of 0.0011028 mol per liter acetic acid is 4.95 × 10–5 S per cm. Calculate its dissociation constant if ^°m for acetic acid is 390.5 S cm2 per mol–1 .