Both CCl4 & CHCl3 have tetrahedral structure but CCl4 is symmetrical while CHCl3 is non-symmetrical.
Due to the symmetric.al structure of CCl4 the resultant of bond dipoles comes out to be zero. But in case of CHCl3 it is not possible as the presence of hydrogen introduces some dissymmetry.
Related Questions:
(1) The Dipole moment of Chloromethane is more than Fluoromethane. Explain.
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