(1) The radius of an atom may be taken as the distance between atomic nucleus and the outermost shell of electrons of the atom.
(2) According
to the Heisenberg’s uncertainty principle the position of a moving electron cannot
be accurately determined. So the distance between the nucleus and the outermost
electron is uncertain.
(3) Atomic
radius can be determined indirectly from inter nuclear distance between the two
atoms in a gaseous diatomic molecule. This internuclear distance between the
two atoms is called bond length.
(4) The
internuclear distance between the two atoms can be measured by X– ray
diffraction or spectroscopic studies and also nuclear magnetic resonance (NMR)
spectrum.
(5) Atomic
radius depends on the type of chemical bond between atoms in a molecule. These
are:
(i) Covalent radius
(ii) Metallic radius or crystal radius
(iii) Vander Waal’s radius
(iv) Ionic radius or Collision radius
(6) Periodicity in
Atomic Radius and Ionic Radius:
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