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Thursday, December 24, 2020

Which of the following is correct order of (B-O) bond length of following compounds? (1) B(OH)3 (2) B(OMe)3 and (3) B(Me)2OH

 SOLUTION:


Extent Back Bonding is   3>1>2 and bond length order is  y>x>z  

Related Questions:

Which of the following correct statement about structure of Ortho boric acid (H3BO3 ) is/are? Statements are as

(1) Angle O-B-O =120   

(2) Angle H-O-B >109 

(3) Hybridization of atom O close to spand   

(4) Molecule is non planer and non polar

Answer: Statement (4) is wrong because molecule is planer and polar


Related Questions:

Tuesday, December 22, 2020

What is the structure of Basic beryllium Nitrate (BBN)?

Basic Beryllium nitrate is a Covalent compound and has as unique structure like [Be4O(NO3)], containg six nitrate group. The more interesting structure of Basic Beryllium nitrate because the nitrate group act as indented ligand in forming a bridge  between two Be atoms.

How to basic beryllium nitrate is obtained from beryllium nitrates?

Their is a unique feature of Beryllium nitrate , on heating at low temperature (125℃) it give Basic Beryllium nitrate , nitrogen gas and oxygen gas but at high temperature (above 1000℃) it give same products like other bivalent nitrate salts.

Why are the properties of CO2 and SiO2 different?

Their properties are very different because CO2 is a chain-like three-atom  molecule and SiO2 is a solid compound with the three dimensional bridges between silicon and oxygen atoms.