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Tuesday, December 29, 2020

Peroxides

The oxides in which  calculated oxidation state of central atom is more than maximum oxidation state of central atom due to the presence of peroxide linkage.

For examples, H2O2, Na2O2, BaO2, PbO2, CrO5 etc.

Suboxides:

The oxides contains more oxygen atoms as compare to central atoms and according to valency requirements of central atoms number of oxygen atoms are not sufficient.

For examples B2O3, C3O2, C12O9, Pb3O, Rb9O2, Cs11O3 etc. 


Mixed Oxides:

The oxides in which oxidation state of oxygen atom is found to be it's uncommon oxidation state on central atom. Mixed oxides on dissolving in water undergo "disproportionation" 

For examples B2O3, ClO2, Cl2O7 , N2O5 , As2Oetc.

Related Questions:

Which oxides (Anhydrides) gives two Oxyacids in water ?

What are the structural difference between oxides ( P4O6 and P4O10) of phosphorous?

What are common structural features of oxides (P4O6 and P4O5) of phosphorous?

Why Nitrogen dioxide (NO2) dimerises to form Dinitrogen tetraoxide (N2O4)?

Why Nitrogen dioxide (NO2) is coloured but Dinitrogen tetraoxide (N2O4) is colourless?

What is product obtained when N2O5 is treated with NaCl?

What are Nature of the alkali metal oxides(O-2), peroxides (O2-2) and superoxides (O-1/2) in hydrolysis reactions?

What are the SESQUI OXIDES ? give the examples.

Which is more basic oxide ion (O-2 ) or hydroxide ion( OH- ) and why ?

Perovskite Oxides:

ABO3 type Oxides are also called Perovskite for examples CaTiO3  And BaTiO3.


Sesqui Oxides

The oxides in which number of oxygen atoms pet central atoms is found to be 3/2 .And it may be ionic, covalent or missed oxides.Mostly M2O3 type Oxides (Corundum structure) are sesqui Oxides.  Where M+2= Al, Ga, Ti, V, Cr, Fe, The etc.

Examples , B2O3, N2O3, Al2O3 ( covalent oxide) Fe2O3 (ionic oxide) Pb2O3 (mixed oxide)