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Tuesday, February 11, 2020

Why PCl3 hydrolysed while NCl3 can not be hydrolysed?


PCl3 hydrolysed due to the presence of vacant Orbital in phosphorus atom which can accept lone pair from water molecule while NCl3 cannot hydrolyse due to unavailability of vacant d-orbitals.

Related Questions:

Which is more basic N(CH3)3 or N(SiH3)3 , explain?

Phosphorus can form PCl5 but nitrogen can not form NCl5 why?

Phosphorus forms PCl5 due to availability of vacant d-orbital though white P can extend its oxidation state but this is not applicable in case of N due to unavailability of d-orbitals.

Related Questions:

Which is more basic N(CH3)3 or N(SiH3)3 , explain?

Why PCl3 hydrolysed while NCl3 can not be hydrolysed?