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Wednesday, January 29, 2020

Out of Acet.yl chloride and acetic anhydride, acetic anhydride is preferred for acylation reactions. Explain why?

Both acetyl chloride and acetic anhydride are good acetylating agents, however, acetyl chloride is much more reactive than acetic anhydride and hence with acetyl chloride reactions are very fast and difficult to control , and with acetic anhydride can be controlled easily. Therefore, acetic anhydride is preferred over acetyl chloride for acetylation.

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Highly branched carboxylic acids are less acidic than unbranched acids. Explain why?


The carboxylate ion of the branched chain acids is shielded from solvent molecules and thus resists for resonance whereas unbranched acids having lesser solvation effect shows resonance stabilized anion to show more acidic character.

What is Dunstan's test , How can it use for test Glycerol ?

When phenolphthalein is added to dilute cold solution of borax, a pink colour is produced. When glycerol is mixed in it, in cold, the colour disappears, but on heating colour reappears. It is a characteristic test of glycerol. This test is called Dunstan's test.

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