Hydrolysis of SF6 is thermodynamically
feasible but due to high activation energy kinetically it is inert towards
hydrolysis. Therefore SF6 is used as inert gas /insulator in
electric devices, which are used as high voltage.
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Tuesday, February 11, 2020
Why PCl3 hydrolysed while NCl3 can not be hydrolysed?
PCl3
hydrolysed due to the presence of vacant Orbital in phosphorus atom which can
accept lone pair from water molecule while NCl3 cannot hydrolyse due to
unavailability of vacant d-orbitals.
Related Questions:
Which is more basic N(CH3)3 or N(SiH3)3 , explain?
Topic:
15th Group : NITROGEN FAMILY
Phosphorus can form PCl5 but nitrogen can not form NCl5 why?
Phosphorus
forms PCl5 due to availability of vacant d-orbital though white P
can extend its oxidation state but this is not applicable in case of N due to unavailability of
d-orbitals.
Why PCl3 hydrolysed while NCl3 can not be hydrolysed?
Related Questions:
Which is more basic N(CH3)3 or N(SiH3)3 , explain?
Topic:
15th Group : NITROGEN FAMILY
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