Hydride: NH3 >
PH3 > AsH3 >SbH3
H-M-H angle: 107 > 92 > 90
> 91 (Degree)
This is due to the decrease in electronegativity
of the central atom of hydride. As the electronegativity decrease the electrons
which were more close to central atom at lower hydrides tends to more far from
it and bp-bp repulsion
decreases.
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