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NCl3 and PCl3 on hydrolysis give different kinds of products. These is because of

(A) Attack of lone pair of water takes place to N and P respectively.

(B) Attack of lone pair of water takes place to Cl and Cl respectively.

(C) Attack of lone pair of water takes place to Cl and P respectively.

(D) None of these

Solution: (C) Their is no vacant d- orbitals hence attack of lone pair of water takes place to Cl and P respectively.

Related Questions:

Question(1): Why aqueous solution of AlCl3 is acidic in nature ?

Question(2): What happen when aq AlCl3 react with Acid or Base?

Question(3): Although anhydrous aluminium chloride is covalent but its aqueous solution is ionic in nature. Why?

Question(4): Arrange in increasing order of extent of hydrolysis [ CCI4, MgCI2, AICI3, PCl5, SiCI4].

Question(5): Although Sulphur contain vacant d-orbital but SF6 does not undergo hydrolysis. Why ?

Question(6): CCl4 can not be hydrolysed but SiCl4 can be. Why?

Question(7): What are the hydrolysis products of urea ?

Question(8): Why SF6 is inert where as SF4 is highly reactive towards H20 ?.

Question(9): Why SF6 behave inert towards hydrolysis?

Question(10): Why PCl3 hydrolysed while NCl3 can not be hydrolysed?

Question(11): Why hydrolysis of NCl3 gives NH4OH and HOCl, while PCl3 on hydrolysis gives H3PO3 and HCl?

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