The hydrolysis of PCl3 may be contrasted with that of NCl3 this difference is due to the change in polarity of P-Cl bond in PCl3 in contrast to N-Cl bond in NCl3.
PF3 is not sensetive to H2O
due to strong P-F bond F being more electronegative than oxygen forms a strong covalent bond with
p in coparison with P-O bond.
Related Questions:
Question(1): Why aqueous solution of AlCl3 is acidic in nature ?
Question(2): What happen when aq AlCl3 react with Acid or Base?
Question(3): Although anhydrous aluminium chloride is
covalent but its aqueous solution is ionic in nature. Why?
Question(4): Arrange in increasing order of extent of hydrolysis [ CCI4, MgCI2,
AICI3, PCl5, SiCI4].
Question(5): Although Sulphur contain vacant d-orbital but SF6 does not undergo
hydrolysis. Why ?
Question(6): CCl4 can not be hydrolysed but SiCl4 can be. Why?
Question(7): What
are the hydrolysis products of urea ?
Question(8): Why
SF6 is inert where as SF4 is highly reactive towards H20
?.
Question(9): Why
SF6 behave inert towards hydrolysis?
Question(10): Why PCl3 hydrolysed while NCl3 can not be hydrolysed?
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