(A) Attack of lone pair of water takes place to N and P respectively.
(B) Attack of lone pair of water takes place to Cl and Cl respectively.
(C) Attack of lone pair of water takes place to Cl and P respectively.
(D) None of these
Solution: (C) Their is no vacant d- orbitals hence attack of lone pair of water takes place to Cl and P respectively.
Related Questions:
Question(1): Why aqueous solution of AlCl3 is acidic in nature ?
Question(2): What happen when aq AlCl3 react with Acid or Base?
Question(3): Although anhydrous aluminium chloride is
covalent but its aqueous solution is ionic in nature. Why?
Question(4): Arrange in increasing order of extent of hydrolysis [ CCI4, MgCI2,
AICI3, PCl5, SiCI4].
Question(5): Although Sulphur contain vacant d-orbital but SF6 does not undergo
hydrolysis. Why ?
Question(6): CCl4 can not be hydrolysed but SiCl4 can be. Why?
Question(7): What
are the hydrolysis products of urea ?
Question(8): Why
SF6 is inert where as SF4 is highly reactive towards H20
?.
Question(9): Why
SF6 behave inert towards hydrolysis?
Question(10): Why PCl3 hydrolysed while NCl3 can not be hydrolysed?
Question(11): Why hydrolysis of NCl3 gives NH4OH and HOCl, while PCl3 on hydrolysis gives H3PO3 and HCl?
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