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Friday, October 16, 2020
What is "COORDINATE BOND" ?
A co-ordinate bond formed between two species by sharing of an electron pair where shared pair electron is given by one but shared by both.
ILLUSTRATIVE EXAMPLE (1):
ILLUSTRATIVE EXAMPLE (1):
ILLUSTRATIVE EXAMPLE (1):
ILLUSTRATIVE EXAMPLE (1):
ILLUSTRATIVE EXAMPLE (1):
CONCLUSIONS:
(1) Atoms of second period elements follow octed rule in doing so either they accept co-ordinate bond or they form co-ordinate bond. However atoms of 3rd period elements perfectly form double bond (pi bond) in the place of co-ordinate bond if direction of co-ordinate bond is from centre to substituent.
(2) If maximum covalency rule applied and pi bonds have formed then back bond is not considered in species
For example H2SO4 and HClO4 have no back bond there is double bond.
Why all the
tetrahedral Complexes are high spin Complexes?
Why Fe(CO)5 is colourless
while Fe(bipy)(CO)3 is intensely purple in colour ?
Why [Mn(H2O)6]+2 is colourless
although in which Mn+2 ion had five unpaired electrons ?
Why [FeF6]3– is colourless whereas [CoF6]3–
is coloured?
Why [Ni(CN)4]-2 is colourless
while [Ni(H2O)4]-2 is colour although both have +2
oxidation state and 3d8 configuration ?
Classification of oxides on basis of oxygen content:
(1) Normal Oxides:
(2) Sesqui Oxides:
(3) Mixed Oxides:
(4) Peroxides:
(5) Super Oxides:
(6) Suboxides:
(7) Perovskites:
(8) Spinel Oxides:
(9) Cage like Oxide:
(1) Normal oxides:
The Oxides in which oxidation state of central atom is found to be
one of the it's common oxidation state. The are also called acid anhydride
because on dissolving them into water oxygen acid is formed in which
oxidation state of central atom is found to be same as present in Oxide.
examples: B2O3,
CO2, N2O3, N2O5, SO2,
SO3, Cl2O7, XeO3, XeO4
etc.
(2) Sesqui oxides:
The oxides in which number of oxygen atoms pet central atoms is
found to be 3/2 .And it may be ionic, covalent or missed oxides.Mostly M2O3
type Oxides (Corundum structure) are sesqui Oxides. Where M+2= Al, Ga, Ti, V, Cr, Fe,
The etc.
Examples , B2O3, N2O3,
Al2O3 ( covalent oxide) Fe2O3
(ionic oxide) Pb2O3 (mixed oxide)
(3) Mixed Oxides:
The oxides in which oxidation state of oxygen atom is found to be
it's uncommon oxidation state on central atom. Mixed oxides on dissolving in
water undergo "disproportionation"
For examples B2O3, ClO2,
Cl2O7 etc.
(4) Peroxides:
The oxides in which calculated oxidation state of central
atom is more than maximum oxidation state of central atom due to the presence
of peroxide linkage.
For examples, H2O2, Na2O2,
BaO2, PbO2, CrO5 etc.
(5) Super Oxides:
The oxides in which
oxidati state of oxygen atom always -1/2, and super oxides are always ionic and
paramagnetic.
For
examples KO2 , PbO2, (NH4)O2 etc.
KO2 =>
k+[O-O]-. Have following character
Bond pair -2
Lone pair -2
Hybri- sp2, linear non
planner and bond angle not applicable.
(6) Suboxides:
The oxides contains more oxygen atoms as compare to central atoms
and according to valency requirements of central atoms number of oxygen atoms
are not sufficient.
For examples B2O3, C3O2,
C12O9, Pb3O, Rb9O2, Cs11O3
etc.
(7) Perovskite
oxides:
ABO3 type Oxides are also called Perovskite for examples CaTiO3 And
BaTiO3.
(8) Spinel Oxide:
(7) Case Oxides:
P4, P4O4,
P4O10, P4S3, P4S10,
N4(CH2)6