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Thursday, October 1, 2020

Calculate the % of available chlorine in the sample in a sample of 3.35 gm of bleaching powder which was dissolved to 100 ml water. 25 ml of this solution on treatment react with KI and dilute acid. Required 20 ml 0.125 N Hypo solution (Sodiumthiosulphate- Na2S2O3).

Related Questions:

What are the Antichlor ?

An antichlor  is a substance used to decompose residual hypochlorite or chlorine after use of chlorine based bleaching , in order to prevent ongoing reactions .example s of antichlor – Sodiumbisulphite (NaHSO3), Pottassiumbisulphite (KHSO3) ,  Sodiummetasulphite (Na2S2O3), Sodiumthiosulphate  (Na2S2O3) and hydrogen peroxide (H2O2).

If trace of chlorine are not remove from pulp used for paper manufacturing,then on the long standing it weaken the paper and makes it yellowish. 

Related topics: 

Mole concept and Stiochiometry

MOLE-MOLE ANALYSIS

 CONCEPT OF LIMITING REAGENTS 

GRAVIMETRY-WEIGHT WEIGHT ANALYSIS

 OLEUM AND ITS PERCENTAGE(%) LABBELING

VOLUME STRENGTH OF H2O2(aq) 

 PRINCIPLE OF ATOM CONSERVATION (PAOC) 

 GRAVIMETRY-WEIGHT WEIGHT ANALYSIS 

EUDIOMETRY-VOLUME VOLUME ANALYSIS OF GAS 

DEGREE OF HARDNESS OF HARD WATER 

PERCENTAGE YIELD OF CHEMICAL REACTION: 

PERCENTAGE PURITY OF GIVEN SAMPLE:

PERCENTAGE (%) AVAILABLE CHLORINE IN BLEACHING POWDER:

 

 

If 4 gm of bleaching powder dissolved to give 100 ml solution 25 ml of it react with excess of CH3COOH and KI .The Iodine liberation required 10 ml of 0.125 N Hypo solutions. Calculate % of available chlorine in the sample.

Available chlorine in sample of bleaching powder can be calculated as per the following reactions.



How to distinguise between " Extensive and Intensive" thermodynamic properties?

 Extensive and Intensive properties:

1: Extensive properties are additive but intensive properties are non additive.
2: Ratio of two extensive property gives an intensive property.

3: An extensive property can be converted into intensive property by defining it per mole/        per gram/ per liter

 

Related Questions:

What are the "State functions or State variables" ?

What are the Mathmatical conditions for state functions or state variables? 

What are the path function in thermodynamics ?

What are the path function in thermodynamics ?

 

 

What are properties of "thermodynamic system"?

 

The state of a system is defined by a particular set of its measurable parameters called properties, by which a system can be described for example, Temperature (T), Pressure (P) and volume (V) defines the thermodynamics state of the system.

Intensive property: After specifying the parameter of the system, when system is divided in parts the parameter whose value remains unchanged due to division is known as Intensive parameter or properties. the value of intensive  is independent of the  mass (size or quantity) of the system.
 Refractive index
Surface tension
Viscosity
Molar Mass
Density
Free energy per mole
Specific heat capacity
Molar heat capacity
Free energy per mole
Pressure (P)
Temperature (T)
Boiling point
freezing point etc
Molar enthalpy
Molar conductivity
Equivalent conductivity
Molarity, Normality, Mole fraction,%w/w,%V/V
EMF of cell
 

Extensive property: the parameter  whose value change on division known as extensive properties and these are depends on the mass (size, quantity) of the system.
Volume  
Number of moles     
Mass
Mole 
Free Energy (G)
Entropy (S)      
Enthalpy (H)   
Internal energy (E&U)   
Heat capacity
K.E.
P.E.
Gibbs free energy (G)
Resistance
Conductance

Extensive and Intensive properties:

1: Extensive properties are additive but intensive properties are non additive.
2: Ratio of two extensive property gives an intensive property.
3: An extensive property can be converted into intensive property by defining it per mole/        per gram/ per liter