(A) Solvolytic reaction takes place in liquid solvents like SO2 and NH3
(B) Acid –Base reaction in liquid (SO3):
Tuesday, May 4, 2021
Auto ionization of anhydrous Sulphuric acid:
Anhydrous sulphuric acid is an acidic Solvent the main auto ionization is
(1) The Mobility of H3SO4+ and HSO4- are comparable to H3O+ and OH- and most of acid accept H+ from H2SO4 and thus behave as base. For example H2PO4 and HNO3 .
(2) HClO4 and HFSO3 are very strong acid in water but very poor weak acid in sulphuric acid.
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Solvolysis in liquid NH3 (Ammonolysis):
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B-F bond length in BF3 is shorter than B-F bond length in (BF4)- why?
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