Covalent and co-ordinate.
(2) What is the temperature at density of water is maximum ?
Covalent and co-ordinate.
Water is a polar compound with a high dielectric constant (81).
Hence, it decreases the electrostatic forces of attraction acting between the
oppositely charged ions in an electrovalent compound. Therefore, the ions are
separated and dissolution occurs. Dissolution of electrolytes in water is also
favoured due to hydration of ions.
Oxidation state of sulphur atom and respective oxy-acids:
Oxidation state | Series name | Prefix of acid | Name of acids |
(+2) | “us”series | Hypo | Hyposulphurous acid |
(+4) | “us”series | ……. | Sulphurous acid |
(+5) | “ic”series | Hypo | Hyposulphuric acid |
(+6) | “ic”series | ……. | Sulphuric acid |
(+7)/(+8)Cal/ava | “ic”series | Peroxy | Peroxysulphuric acid |
Important Note:
(1) Ortho and meta form of sulphurous and sulphuric acid not exist but both have pyro form only.
(2) Hyposulphurous acid start thionous series and while hyposulphuric acid start thionic series;
(1) Sulphurous Series:
(A) Sulphurous acid:
(B) Hyposulphurous acid(H2SO2/S(OH)2):
(C) Thiosulphurous acid(H2S2O2):
(D) Pyrosulphurous acid(H2S2O5=H2SO3+SO2):
(2) Sulphuric acid series:
(A) Sulphuric acid(H2SO4):
(B) Pyrosulphuric acid(H2S2O7=H2SO4+SO3): Oleum:
(C) Peroxomonosulphuric acid(H2SO5):Caro’s acid:
(D) Peroxodisulphuric acid(H2S2O8): Marshall’s acid:
(3) Thionous acid series
(4) Thionic acid series:
(A) Dithionic acid(H2S2O6):
(B) Trithionic acid (H2S3O6):
(C) Tetrathionic acid(H2S4O6):
(2) What are "Ortho" or "Meta" oxyacids?
(3) What are "pyro" oxy acids?
Related Questions:
(1) What is Use of Boric Acid?
(2) What is use of Orthoboric acids?
(3) What is basicity of "Boric acid" ?
(4) Why Boric acid exist in solid state ?
(5) What is structure of solid Ortho Boric acid ?
(6) What is effect of heat on Borax?
(7) What is the structure of trimetaboric acid and trimetaborate ion?
(8) What is the Sodium per borate ,give the structure and its uses?
(9) Why aqueous solution of borax reacts with two moles of acids ?
(10) What is the molecular formula of Borax ?
(11) Why Boric acid become strong acid in the presence of cis 1,2-diol or 1,3-diol ?
(12) Why Borazine is more reactive than benzene towards Electrophic Aromatic substitution reactions ?
(13) Why Borazine (B3N3H6) is also known as inorganic benzene ?.
In chlorine, the radii mean the atomic or covalent radii which is actually half the intermolecular distance between 2 atoms whereas in Argon the radii means the Vander waals radii as Argon is not a diatomic molecule. Vander Waal’s radii are actually half the distance between adjacent molecule. So Vander Waal’s radii being larger than atomic radii, Argon has a larger radii than chlorine.
(1) The radius of an atom may be taken as the distance between atomic nucleus and the outermost shell of electrons of the atom.
(2) According
to the Heisenberg’s uncertainty principle the position of a moving electron cannot
be accurately determined. So the distance between the nucleus and the outermost
electron is uncertain.
(3) Atomic
radius can be determined indirectly from inter nuclear distance between the two
atoms in a gaseous diatomic molecule. This internuclear distance between the
two atoms is called bond length.
(4) The
internuclear distance between the two atoms can be measured by X– ray
diffraction or spectroscopic studies and also nuclear magnetic resonance (NMR)
spectrum.
(5) Atomic
radius depends on the type of chemical bond between atoms in a molecule. These
are:
(i) Covalent radius
(ii) Metallic radius or crystal radius
(iii) Vander Waal’s radius
(iv) Ionic radius or Collision radius
(6) Periodicity in
Atomic Radius and Ionic Radius:
Related Questions: