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Saturday, October 10, 2020

What is oleum formula?

(1) Oleum can be represented by the formulaySO3.H2O where y is the total molar sulphur trioxide content .the value of y can be varied to different Oleum sample.
(2) 
Oleum also be expressed  as H2SO4.xSO3where x is molar free suphur trioxide.
(3) 
Oleum is the solution of of sulphur trioxide in sulphuric acid , it is also known as  fuming sulphuric acid or Pyrosulphuric acid(H2S2O7=H2SO4+SO3).
(4) 
Oleum sample contain two type of SO3.

(i) Free SO3:- It is that SO3 which combined with water water to give H2SO4 .
(ii) Combined SO3:- The SO3 which is present in H2SO4 itself is known as combined SO3 and it does not react with water.

What is Oleum ?

1) Oleum can be represented by the formulaySO3.H2O where y is the total molar sulphur trioxide content .the value of y can be varied to different Oleum sample.
(2) Oleum also be expressed  as H2SO4.xSO3where x is molar free suphur trioxide.
(3) Oleum is the solution of of sulphur trioxide in sulphuric acid , it is also known as  fuming sulphuric acid or Pyrosulphuric acid(H2S2O7=H2SO4+SO3).
(4) Oleum sample contain two type of SO3.

(i) Free SO3:- It is that SO3 which combined with water water to give H2SO4 .
(ii) Combined SO3:- The SO3 which is present in H2SO4 itself is known as combined SO3 and it does not react with water.

Thursday, October 8, 2020

Why dipole moment of CO2 is why?


The structure of CO2 is this is a highly symmetrical structure with a plane of symmetry passing through the carbon. The bond dipole of C–O is directed towards oxygen as it is the negative end. Here two equal dipoles acting in opposite direction cancel each other and therefore the dipole moment is zero.




Why dipole moment of H2O greater thna F2O ?

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Let’s draw the structure of both two compounds and then analyses it.
                                
In both H2O and F2O the structure is quite the same. In H2O as O is more electronegative than hydrogen so the resultant bond dipole is towards O, which means both the lone pair and bond pair dipole are acting in the same direction and dipole moment of H2O is high. In case of F2O the bond dipole is acting towards fluorine, so in F2O the lone pair and bond pair dipole are acting in opposition resulting in a low dipole


Why polarity of Ammonia (NH3) is more than NF3 ?