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Tuesday, July 2, 2019

Oxyacids of Nitrogen :



S.N.
Formula
Name of acids
Oxidation No. of N

1
H2N2O2 or HNO
Hyponitrous acid
+1
2
H4N2O4 or H2NO2
Hydroxynitrous acid
+2
3
HONO or HNO2
Nitrous acid
+3
4
HOONO
Pernitrous acid
+4
5
HNO3
Nitric acid
+5
6
HNO4
Pernitric acid
+6
 (1) Hyponitrous acid (H2N2O2):
 Hyponitrous acid is a chemical compound with formula H2N2O2 or HON=NOH. Hyponitrous acid is a weak acid in aqueous solution and decomposes to N2O and water. It is an isomer of nitramide [H2N−NO2].
Hyponitrous acid forms two series of salts, the hyponitrites containing the [ON=NO]2− anion, and the "acid hyponitrites" containing the [HON=NO]−anion.
           

(2) Nitrous acid (HNO2):
Nitrous acid (HNO2) is a weak and monobasic acid known only in solution and in the form of nitrite (NO2−) salts. Nitrous acid is used to make diazonium salts from amines. The resulting diazonium salts are reagents in azo coupling reactions to give azo dyes.
      

(3) Nitric acid (HNO3):
Nitric acid is also known as aqua fortis (meaning strong water) which was given by alchemists.
 
Related Questions:



Trisilyl amine, N(SiH3)3 is planar whereas trimethyl amines N(CH3)3 is pyramidal. Explain why?.














           

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