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How is basicity order determined?

According to "Lewis acid base concept base are those substance which can donate lone pair or can accept H+ ions" Basicity order of base determined on the basis of lp donation power of base. 
For example amine are  the  base due to the presence of lone pair on nitrogen atom.
Order of basicity of amines are as follow:
           3°>2°>1° (gaseous state only)
3° amines are more basic due to high density of electron on nitrogen atom hence it can easily donate lp to the acid or H+
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