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Tuesday, December 29, 2020

The Solvent system(Self or Auto Ionization of Solvents)

The most common concept of acids and bases is due to Cady and Elsey. Most of the solvents undergo auto-ionization and form cation and anions like water, regardless it contains protons or not for examples; H2O, NH3, H2SO4, HNO3, POCl3, BrF3, N2O4, NOCl, CH3COOH,

  1. Solvolysis in liquid N2O4:
  2. Hydrolysis reactions:
  3. Solvolysis in liquid NH3 (Ammonolysis):
  4. Auto ionization of anhydrous Sulphuric acid:
  5. Solvolysis in Liquid SO3:
  6. Solvolysis in Liquid HF:

 Related Questions: 

Why aqueous solution of AlCl3 is acidic in nature ?

What happen when aq AlCl3 react with Acid or Base?

Although anhydrous aluminium chloride is covalent but its aqueous solution is ionic in nature. Why?

Why BF3 do not exist as dimer?. Explain.

Why B-F bond length in BF3 is shorter (130 pm) than B-F bond Iength in BF4- (143 pm)?. Explain.

B-F bond length in BF3 is shorter than B-F bond length in (BF4)- why?

When B2H6 is allowed to react with following Lewis bases, then how may given Lewis base form adduct through symmetrical Cleavage of B2H6.

What is product of reaction between diborane (B2H6) and ammmonia (NH3)?

Why methylation of Diborane (B2H6) replace four hydrogen only ?

What is Use of Boric Acid?

What is use of Orthoboric acids?

What is basicity of "Boric acid" ?

Why Boric acid exist in solid state ?

What is structure of solid Ortho Boric acid ?

What is effect of heat on Borax?

What is the structure of trimetaboric acid and trimetaborate ion?

What is the Sodium per borate ,give the structure and its uses?

Why aqueous solution of borax reacts with two moles of acids ?

What is the molecular formula of Borax ?

Why Boric acid become strong acid in the presence of cis 1,2-diol or 1,3-diol ?

Why Borazine is more reactive than benzene towards Electrophic Aromatic substitution reactions ?

Why Borazine (B3N3H6) is also known as inorganic benzene ?.

Four-center two-electron bond (4C-2e Bond): Structure of AlCl3:

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