The differences in the properties of the first member of a group from those of the other members are due to
(i) the smaller size of atom.
(ii) presence of one inner shell of two electrons and
(iii) absence of d – orbitals.
(1) NCl5 (due to absence of
d-orbitals)
(2) BiCl5 (Bi5+ being an oxidizing
agent oxidizes Cl ion to Cl2 and Cl- ion being a reducing
agent reduces Bi5+ to Bi3+).